Tribenzosubporphines: Synthesis and characterization
Tribenzosubporphines: Synthesis and characterization
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DOI：
10.1002/anie.200503426
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Osuka, A
中科院分区：
文献类型：
--
作者：
Inokuma, Y;Kwon, JH;Osuka, A
（图所示）保持在家族中：与硼酸模板的一锅缩合可合成亚卟啉硼（III）配合物（见例子；B绿，O红，N蓝，C绿松石，H白），卟啉的环状收缩同系物。易轴向配体交换反应提供烷氧基和羧基配位的亚卟啉，它们具有碗状结构，碗状深度取决于轴向基团。
(Figure Presented) Keeping it in the family: A one-pot condensation with a boric acid template leads to the synthesis of subporphineboron (III) complexes (see example; B green, O red, N blue, C turquoise, H white), ring-contracted congeners of porphyrins. Facile axial ligand exchange reactions provide alkoxy-and carboxy-coordinated subporphyrins, which have bowl-shaped structures with a bowl depth that depends on the axial group.