Multi-alkylthienyl appended porphyrins for efficient dye-sensitized solar cells

Multi-alkylthienyl appended porphyrins for efficient dye-sensitized solar cells
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用于高效染料敏化太阳能电池的多烷基噻吩附加卟啉

DOI:
10.1016/j.dyepig.2011.05.017
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发表时间:
2011-12
期刊:
影响因子:
4.5
通讯作者:
Tan, Songting
Tan, Songting
中科院分区:
材料科学2区
文献类型:
--
作者:
Zhou, Weiping;Zhao, Bin;Shen, Ping;Jiang, Shenghui;Huang, Hongduan;Deng, Lijun;Tan, Songting

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Four porphyrin dyes, incorporating multi-alkylthienyl appended porphyrins as the electron donor, the 2-cyanoacrylic acid as the electron acceptor, and different π-conjugated spacer, have been synthesized for dye-sensitized solar cells (DSSCs). All the porphyrin dyes studied in this work exhibit red-shifted and broadened electronic spectra respect to the reference PZnas expected. By the introduction of thienyl groups at the meso-positions, the energy level of Eox(excited-state oxidation potentials) is significantly shifted to the positive compared with the reference PZn, indicating a decreased HOMO–LUMO gap. The highest power conversion efficiency of the four dyes based on DSSCs reached 5.71% under AM 1.5 G irradiation.
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