New Formulas for Zincate Chemistry: Synergistic Effect and Synthetic Applications of Hetero-bimetal Ate Complexes.
New Formulas for Zincate Chemistry: Synergistic Effect and Synthetic Applications of Hetero-bimetal Ate Complexes.
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锌酸盐化学新配方：异质双金属Ate配合物的协同效应和合成应用。
DOI：
10.1007/3418_2013_72
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
Masanobu Uchiyama,* Chao Wang
中科院分区：
文献类型：
--
作者：
Yo Hamada;Kohsuke Gonda;Noriaki Ohuchi;Masanobu Uchiyama,* Chao Wang
有机锌酸盐是化学史上最古老的一类有机金属化合物。它们特殊的分子结构导致协同作用，从而产生独特的化学性质。因此，这些化合物引起了当今有机金属化学家的广泛关注，并被广泛用作各种功能分子的有效合成工具。作为一个代表性的例子，锌酸锂呈现出许多优点，例如容易制备、可调节的反应性/选择性以及多样化的适用性。本章概述了锌酸锂的研究进展，包括观察历史、一般表征、制备方法、合成用途以及进一步的应用。
Organozincates are the oldest class of organometallic ate compounds in the history of chemistry. Their special molecular structures lead to synergetic operations which contribute to unique chemical properties. Therefore, these compounds have attracted considerable attention from organometallic chemists nowadays and also have been widely employed as an efficient synthetic tool towards various functional molecules. As a representative example, lithium zincates present many advantages such as easy preparation, adjustable reactivity/selectivity as well as diversified applicability. This chapter provides an overview of the research advances on lithium zincate, including observation history, general characterization, preparative methods, synthetic utilities as well as further applications.