Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR
Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR
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DOI：
10.1039/d0cp01216e
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发表时间：
2020-07-14
影响因子：
3.3
通讯作者：
Nakamura, Koichi
中科院分区：
文献类型：
--
作者：
Inukai, Munehiro;Kurihara, Takuya;Nakamura, Koichi
The application of high-resolution NMR analysis for CO2 adsorbed in a MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had an unusually slow mobility (tau similar to 10(-8) s). CO2-CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at the adsorption sites.
