The ion pair distribution functions in molten rubidium chloride
The ion pair distribution functions in molten rubidium chloride
复制标题
熔融氯化铷中的离子对分布函数
DOI：
10.1080/14786437608222045
复制
发表时间：
1976
影响因子：
1.6
通讯作者：
R. Stewart
中科院分区：
文献类型：
--
作者：
E. Mitchell;P. F. J. Poncet;R. Stewart
用中子散射法测定了熔融氯化铷的部分对分布函数。Cl同位素从天然丰度的35Cl和37Cl变化到富集的35Cl和富集的37Cl。通过使用特制的钒容器，实现了比其它卤化物工作中使用的二氧化硅容器更简单的容器散射校正。将计算结果与狄克逊和Sangster的分子动力学模拟结果进行了比较，吻合较好。
Abstract The partial pair distribution functions for molten rubidium, chloride have been determined by neutron scattering from isotopically doped samples. The Cl isotope was varied from the natural abundance for 35Cl and 37Cl to enriched 35Cl and enriched 37Cl. By using a specially prepared vanadium container, a much simpler container scattering correction was achieved compared with that for the silica container used in other work on halides. The results are compared with the molecular dynamics simulation of Dixon and Sangster: the agreement is good.