A versatile aqueous reduction of bio-based carboxylic acids using syngas as a hydrogen source.
A versatile aqueous reduction of bio-based carboxylic acids using syngas as a hydrogen source.
复制标题
DOI：
10.1002/cssc.201200674
复制
发表时间：
2013
期刊：
影响因子：
8.4
通讯作者：
Lei Yu;Xianlong Du;Jing Yuan;Yongmei Liu;Yong Cao;Heyong He;Kangnian Fan
中科院分区：
文献类型：
--
作者：
Lei Yu;Xianlong Du;Jing Yuan;Yongmei Liu;Yong Cao;Heyong He;Kangnian Fan
合成气作为一种多用途的氢源：利用容易获得且经济上有利的合成气作为一种方便的氢源，在一个由耐酸的单相单斜氧化锆(Au/m-ZrO(2))负载的金纳米颗粒组成的高度坚固的催化剂系统上，实现了生物基羧酸的高效和可持续的水相还原。一系列基于生物的多功能羧酸已被选择性地转化为相应的内酯或二醇，产率高到极高。
Syngas as a versatile hydrogen source: Using readily available and economically favorable syngas as a convenient hydrogen source, an efficient and sustainable aqueous reduction of bio-based carboxylic acids has been achieved over a highly robust catalyst system consisting of gold nanoparticles supported on acid-tolerant single-phase monoclinic zirconia (Au/m-ZrO(2)). A range of bio-based multifunctional carboxylic acids have been selectively converted into their corresponding lactones or diols in high to excellent yields.