First Discovery of Tetravalent Ti4+ Ion Conduction in a Solid

First Discovery of Tetravalent Ti4+ Ion Conduction in a Solid
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DOI:
10.1021/cm803193k
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发表时间:
2009-02
影响因子:
8.6
通讯作者:
Naoyoshi Nunotani;S. Tamura;N. Imanaka
Naoyoshi Nunotani;S. Tamura;N. Imanaka
中科院分区:
材料科学2区
文献类型:
--
作者:
Naoyoshi Nunotani;S. Tamura;N. Imanaka

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纯四价Ti 4+离子在固体中的导电性首先在具有三维NASICON型结构的Ti(Nb 1 −xWx)5/(5+x)(PO 4)3(x ≤ 0.2)固体中得到证实。严格选择晶体结构和组成元素使得Ti(Nb0.8W0.2)5.0/5.2(PO 4)3固体具有高的Ti 4+离子电导率。
Pure tetravalent Ti4+ ion conduction in solids was first demonstrated for the Ti(Nb1−xWx)5/(5+x)(PO4)3 (x ≤ 0.2) solid with a three-dimensional NASICON-type structure. Strict selection of the crystal structure and constituent elements enabled high Ti4+ ion conductivity for the Ti(Nb0.8W0.2)5.0/5.2(PO4)3 solid.