LUMINESCENCE AND ENERGY TRANSFER IN SOLUTIONS OF RARE EARTH COMPLEXES .2. STUDIES OF SOLVATION SHELL IN EUROPIUM(3) AND TERBIUM(3) AS A FUNCTION OF ACETATE CONCENTRATION
LUMINESCENCE AND ENERGY TRANSFER IN SOLUTIONS OF RARE EARTH COMPLEXES .2. STUDIES OF SOLVATION SHELL IN EUROPIUM(3) AND TERBIUM(3) AS A FUNCTION OF ACETATE CONCENTRATION
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DOI：
10.1021/j100862a003
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发表时间：
1967-01-01
影响因子：
--
通讯作者：
WINDSOR, MW
中科院分区：
文献类型：
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作者：
KROPP, JL;WINDSOR, MW
The fluorescence yield and fluorescence lifetime of rare earth ions in solution are a function of the environment about the ion, being dependent upon the nature, number, and arrangement of the molecules present in the coordination shell of the ion. We have shown previously (part I of this series) that the dominant mode of quenching for excited rare earth ions in solution occurs via coupling of the electronic excitation to OH and CH vibrations in the solvation shell and that the rate constant for quenching is proportional to the number of bonds of each species present. 1 We showed
