Design of highly thermal-shock resistant tungsten alloys with nanoscaled intra- and inter-type K bubbles

Design of highly thermal-shock resistant tungsten alloys with nanoscaled intra- and inter-type K bubbles
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具有纳米级K型内和间气泡的高抗热震钨合金的设计

DOI:
10.1016/j.jallcom.2018.12.168
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发表时间:
2019-04
影响因子:
6.2
通讯作者:
Chain-Tsuan Liu
Chain-Tsuan Liu
中科院分区:
材料科学2区
文献类型:
--
作者:
Bo Huang;Jun Tang;Longqing Chen;Xiaoliang Yang;Youyun Lian;Lei Chen;Xiang Liu;Xudong Cui;Lin Gu;Chain-Tsuan Liu

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具有高强度、高韧性和高温稳定性的钨合金在极端条件下是迫切需要的。纳米工程的钾泡(5-50 nm)是一个迷人的策略,以加强这些性质。然而,这种纳米钾泡目前只能通过挤压和拉丝工艺在钨丝中获得。本文报道了一种采用铝钾硅(AKS)掺杂和火花等离子烧结(SPS)相结合的工业应用工艺制备的钾内和钾间纳米气泡增强体钨,该材料具有理想的强度和显著的韧性,以及高的抗热震性。aks掺杂将K- al - si - o颗粒掺入W晶粒内,SPS的快速高温烧结使K- al - si - o颗粒产生纳米K泡,并使K泡保持在W晶粒内。我们的k泡强化钨材料在高温应用中显示出很高的潜力。这种策略也可能适用于其他难熔金属,如钼。
Tungsten alloys with high strength, high toughness and high-temperature stability are strongly desired in extreme conditions. The nanoengineering of potassium bubbles (5–50 nm) is a fascinating strategy to strengthen these properties. However, such nano potassium bubbles can only be acquired in tungsten wires through swaging and drawing process till now. Here, we report an intra- and inter-potassium nano-bubbles strengthened bulk tungsten fabricated via an industrially applicable process combining aluminum-potassium-silicon (AKS) doping and spark plasma sintering (SPS), which exhibits desirable strength and remarkable toughness, as well as high thermal-shock resistance. The AKS-doping incorporated the K-Al-Si-O particles inside the W grains and the rapid high-temperature sintering of SPS produced the nanometer K bubbles from the K-Al-Si-O particles and kept the K bubbles inside the W grains. Our K-bubble strengthened tungsten material displays high potential in high-temperature applications. This strategy is also potentially applicable to other refractory metals such as molybdenum.
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