A total synthesis of (+)-preussin and its 5-epimer
A total synthesis of (+)-preussin and its 5-epimer
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DOI：
10.1002/cjoc.19980160513
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发表时间：
2010-08
影响因子：
5.4
通讯作者：
Dong Han-qing;Lin Guo-qiang
中科院分区：
文献类型：
--
作者：
Dong Han-qing;Lin Guo-qiang
以二乙烯基甲醇（3）为原料，经Sharpless不对称环氧化和PDC氧化环化反应合成了（+）-普鲁辛（1）及其5-差向异构体。
(+)-Preussin (1) and its 5-epimer were synthesized from the divinylcarbinol (3) with Sharpless asymmetric epoxidation of 3 and the oxidative cyclization of 9 with PDC as the key steps.