Fluorine Bomb Calorimetry. XVI. The Enthalpy of Formation of Boron Nitride1,2
Fluorine Bomb Calorimetry. XVI. The Enthalpy of Formation of Boron Nitride1,2
复制标题
DOI：
10.1021/j100873a002
复制
发表时间：
1966
期刊：
影响因子：
--
通讯作者：
S. Wise;J. Margrave;H. Feder;W. Hubbard
中科院分区：
文献类型：
--
作者：
S. Wise;J. Margrave;H. Feder;W. Hubbard
在燃烧弹热量计中测量氮化硼在氟中的燃烧能量。该值与通过类似方法测定的 BF3 的生成热结合起来，得到标准生成热 AHf’sgs。 u，六方BN。所得值——59.97±0.87 kcal。摩尔-1，与最近通过其他方法进行的一些测定非常一致。
The energy of combustion of boron nitride in fluorine was measured in a combustion bomb calorimeter. This value was combined with the enthalpy of formation of BF3, determined by a similar method, to give the standard enthalpy of formation, AHf’sgs. u, of hexagonal BN. The value obtained,—59.97±0.87 kcal. mole-1, is in excellent agreement with several recentdeterminations by other methods.