Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelate.
Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelate.
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交换螯合物图片：NaHoDOTMA（一种“半”水合螯合物）的晶体结构。
DOI：
10.1039/c3cc38814j
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发表时间：
2013
期刊：
影响因子：
--
通讯作者：
Woods,Mark
中科院分区：
文献类型：
--
作者：
Payne,KatherineM;Valente,EdwardJ;Aime,Silvio;Botta,Mauro;Woods,Mark
晶体学通常仅提供静态结构信息。这可能使其成为探测动态解状态过程的无效技术。 HoDOTMA 晶体提供了独特的结构，有效地代表了水交换过程中的镧系元素四乙酸盐螯合物的结构。
Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.