The Structure of "R2Cu(CN)Li2" Lithium Cuprates: Lower-Order Aggregates of Gilman Reagents and Organo Lithium Compounds
The Structure of "R2Cu(CN)Li2" Lithium Cuprates: Lower-Order Aggregates of Gilman Reagents and Organo Lithium Compounds
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“R2Cu(CN)Li2”铜酸锂的结构：吉尔曼试剂和有机锂化合物的低阶聚集体
DOI：
10.1021/jo00089a001
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发表时间：
1994
影响因子：
3.6
通讯作者：
B. E. Rossiter
中科院分区：
文献类型：
--
作者：
J. Snyder;D. Spangler;R. BehlingJames;B. E. Rossiter
对由结构式（CH 3）2Cu（CN）Li 2表示的铜酸锂的分子轨道研究强烈表明，该化合物最好被描述为通过与1摩尔CH 3 Li或CN Li形成环而络合的低阶Gilman铜酸盐，而不是三配位Cu（I）«高阶»氰基铜酸盐
A molecular orbital study of lithium cuprates represented by the constitutional formula (CH 3 ) 2 Cu(CN)Li 2 strongly suggests that the compounds are best described as lower-order Gilman cuprates complexed by ring formation with 1 mol of either CH 3 Li or CNLi rather than as tricoordinate Cu(I) «higher-order» cyanocuprates