The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl-organic framework
The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl-organic framework
复制标题
独特类型四核铀酰介导的双重互穿铀酰有机框架的模板合成
DOI：
10.1039/c5cc09314g
复制
发表时间：
2016
影响因子：
4.9
通讯作者：
Shi Wei-qun
中科院分区：
文献类型：
--
作者：
An Shu-wen;Mei Lei;Hu Kong-qiu;Xia Chuan-qin;Chai Zhi-fang;Shi Wei-qun
以半刚性羧酸H2 dbsf为原料，有机碱bpp为电荷平衡剂和堆积模板剂（H2 dbsf = 4，4 ′-二羧基联苯砜，bpp = 1，3-二（4-吡啶基）丙烷），水热合成了两种新型四核铀酰介导的双层互穿网络[U4 O 10（dbsf）3]2[H2 bpp]2和[U4 O 10（dbsf）3][H2 bpp].
Two novel tetra-nuclear uranyl-mediated two-fold interpenetrating networks, [U4O10(dbsf)3]2[H2bpp]2 and [U4O10(dbsf)3][H2bpp], have been hydrothermally synthesized from a semi-rigid carboxylic acid, H2dbsf, with the organic base, bpp, as the charge balancing agent and stacking template (H2dbsf = 4,4′-dicarboxybiphenyl sulfone, bpp = 1,3-di(4-pyridyl)propane).