Ferrocene clicked poly(3,4-ethylenedioxythiophene) conducting polymer: Characterization, electrochemical and electrochromic properties
Ferrocene clicked poly(3,4-ethylenedioxythiophene) conducting polymer: Characterization, electrochemical and electrochromic properties
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DOI：
10.1016/j.elecom.2009.08.031
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发表时间：
2009-10
影响因子：
5.4
通讯作者：
Jingjing Xu;Yuan Tian;Ru Peng;Y. Xian;Q. Ran;L. Jin
中科院分区：
文献类型：
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作者：
Jingjing Xu;Yuan Tian;Ru Peng;Y. Xian;Q. Ran;L. Jin
The “click” chemistry, Cu(I)-catalyzed azide–alkyne cycloaddition reaction, was applied to covalently functionalize the poly(3,4-ethylenedioxythiophene) (PEDOT) conducting polymer film with an excellent electron transfer mediator (ferrocene). Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and Raman spectroscopy were used to characterize the ferrocene-grafted PEDOT conducting polymer film, and it was proved that the grafting procedure via click reaction had a high efficiency. The ferrocene groups covalently grafted in the polymer films turned out to own a relatively fast electron transfer rate and show multi-color states via adjusting applied potential.
