Fluorescent or not? Size-dependent fluorescence switching for polymer-stabilized gold clusters in the 1.1-1.7 nm size range.

Fluorescent or not? Size-dependent fluorescence switching for polymer-stabilized gold clusters in the 1.1-1.7 nm size range.
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DOI:
10.1039/b809876j
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发表时间:
2008-08
影响因子:
4.9
通讯作者:
N. Schaeffer;B. Tan;C. Dickinson;M. Rosseinsky;A. Laromaine;D. McComb;M. Stevens;Yiqian Wang
N. Schaeffer;B. Tan;C. Dickinson;M. Rosseinsky;A. Laromaine;D. McComb;M. Stevens;Yiqian Wang
中科院分区:
化学2区
文献类型:
--
作者:
N. Schaeffer;B. Tan;C. Dickinson;M. Rosseinsky;A. Laromaine;D. McComb;M. Stevens;Yiqian Wang

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介绍了在设计的聚合物配体存在下,通过金盐还原合成荧光水溶性金纳米粒子,粒子的大小和荧光由聚合物与金的比例控制,最具荧光的纳米材料具有3%的量子产率,1.1 nm的金核和6.9 nm的流体动力学半径。
The synthesis of fluorescent water-soluble gold nanoparticles by the reduction of a gold salt in the presence of a designed polymer ligand is described, the size and fluorescence of the particles being controlled by the polymer to gold ratio; the most fluorescent nanomaterial has a 3% quantum yield, a 1.1 nm gold core and a 6.9 nm hydrodynamic radius.