dl‐Threoninium tri­chloro­acetate

dl‐Threoninium tri­chloro­acetate
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DOI:
10.1107/s1600536804016630
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发表时间:
2004-08
影响因子:
0.9
通讯作者:
K. Rajagopal;R. D. Franklin;R.V. Krishnakumar;K. Ravikumar;S. Natarajan
K. Rajagopal;R. D. Franklin;R.V. Krishnakumar;K. Ravikumar;S. Natarajan
中科院分区:
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文献类型:
--
作者:
K. Rajagopal;R. D. Franklin;R.V. Krishnakumar;K. Ravikumar;S. Natarajan

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在标题化合物C4 H10 NO3+·C2Cl 3 O2 −(I)中,氨基酸分子以阳离子形式存在,具有带正电荷的氨基和不带电荷的羧酸基团。三氯乙酸分子以阴离子状态存在。苏氨酸阳离子和三氯乙酸阴离子形成氢键双层,通过N-H-O和O-H-O氢键网络连接在一起,并沿着B轴延伸。这些双层之间没有氢键相互作用。在(I)中没有观察到典型的头-尾氢键。
In the title compound, C4H10NO3+·C2Cl3O2−, (I), the amino acid mol­ecule exists in the cationic form, with a positively charged amino group and an uncharged carboxylic acid group. The tri­chloro­acetic acid mol­ecule exists in the anionic state. The threoninium cations and the tri­chloro­acetate anions form hydrogen-bonded double layers, linked together by a network of N—H⋯O and O—H⋯O hydrogen bonds and extended along the b axis. These double layers have no hydrogen-bonded interactions between them. No classic head-to-tail hydrogen bonds are observed in (I).