The exchange reaction between rhenium hexafluoride and boron trichloride and enthalpies of formation of rhenium pentachloride and rhenium hexafluoride
The exchange reaction between rhenium hexafluoride and boron trichloride and enthalpies of formation of rhenium pentachloride and rhenium hexafluoride
复制标题
六氟化铼与三氯化硼的交换反应及五氯化铼和六氟化铼的生成焓
DOI：
10.1039/dt9730000501
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发表时间：
1973
期刊：
影响因子：
--
通讯作者：
R. Peacock
中科院分区：
文献类型：
--
作者：
J. Burgess;C. J. Fraser;I. Haigh;R. Peacock
由水解测定估算了ReCl_5和ReF_6的生成焓分别为-861 ± 0.8kcal·mol ~（-1）和-3226 ± 2.3kcal·mol ~（-1）。在各种条件下，六氟化铀与硼氢化钠的反应已被证明产生六氟化铀作为唯一的主要固相;以前报道的六氟化铀尚未被检测到。
Enthalpies of formation of ReCl5, –86·1 ± 0·8 kcal mol–1, and ReF6, –322·6 ± 2·3 kcal mol–1, have been estimated from hydrolysis measurements. The reaction of rhenium hexafluoride with boron trichloride, under various conditions, has been shown to yield rhenium pentachloride as the only major solid phase; the previously reported hexachloride has not been detected.