Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation.
Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation.
复制标题
DOI：
10.1039/b517585b
复制
发表时间：
2006-05
影响因子：
4.9
通讯作者：
K. Mikami;Kazuki Wakabayashi;Yukinori Yusa;K. Aikawa
中科院分区：
文献类型：
--
作者：
K. Mikami;Kazuki Wakabayashi;Yukinori Yusa;K. Aikawa
基于非手性二苯甲酮的铑配合物的手性可以通过手性二胺来控制，以在酮的催化不对称转移氢化中提供显着高的对映选择性（高达 99% ee，99% 产率）。
The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield).