Diisopropyl [(benzoyl-amino)-(phen-yl)meth-yl]phospho-nate.

Diisopropyl [(benzoyl-amino)-(phen-yl)meth-yl]phospho-nate.
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DOI:
10.1107/s1600536809006382
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发表时间:
2009-02-28
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Zhao YF
Zhao YF
中科院分区:
其他
文献类型:
--
作者:
Fang H;Fang MJ;Xu Y;Yu WC;Zhao YF

文献摘要

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苯甲酰氯与[氨基](苯基)甲基]磷酰二异丙酯反应得到标题化合物C20 H26 NO 4 P。苯甲酰基氨基与苯环平面间的二面角为77.0(2)°。 该晶体结构是通过双键磷酰基O原子和酰胺N原子之间的强分子间N-H-O氢键稳定的,该氢键将分子分子连接成关于对称中心的对。
The title compound, C20H26NO4P, has been obtained by the reaction of benzoyl chloride and diisoprop­yl[amino­(phen­yl)meth­yl]phospho­nate. The dihedral angle between the planes of the benzoyl­amino group and the phenyl ring is 77.0 (2)°. The crystal structure is stabilized by strong inter­molecular N—H⋯O hydrogen bonds between the doubly bonded phosphoryl O atom and the amide N atom which link the mol­ecules into pairs about a center of symmetry.