ORGANOMANGANESE REAGENTS .30. ENANTIOSELECTIVE PREPARATION OF ALPHA-ACYLOXY KETONES FROM ALPHA-HYDROXY AND ALPHA-AMINO-ACIDS
ORGANOMANGANESE REAGENTS .30. ENANTIOSELECTIVE PREPARATION OF ALPHA-ACYLOXY KETONES FROM ALPHA-HYDROXY AND ALPHA-AMINO-ACIDS
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DOI：
10.1016/0040-4039(95)01289-t
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发表时间：
1995-09-04
影响因子：
1.8
通讯作者：
METAIS, E
中科院分区：
文献类型：
--
作者：
CAHIEZ, G;METAIS, E
通过将有机锰试剂与由α-羟基和α-氨基酸制备的相应的α-酰氧基酰氯进行酰化，可以容易地以高收率和优异的对映体纯度制备各种手性α-酰氧基酮。
Various chiral alpha-acyloxy ketones have been easily prepared, in high yields with an excellent enantiomeric purity, by acylation of organomanganese reagents with the corresponding alpha-acyloxy carboxylic acid chlorides prepared from alpha-hydroxy and alpha-amino acids.