THE SYNTHESES OF POTASSIUM SELENOCARBOXYLATES AND THEIR DERIVATIVES
THE SYNTHESES OF POTASSIUM SELENOCARBOXYLATES AND THEIR DERIVATIVES
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硒代羧酸钾及其衍生物的合成
DOI：
10.1246/cl.1976.203
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发表时间：
1976
影响因子：
1.6
通讯作者：
Y. Hirabayashi
中科院分区：
文献类型：
--
作者：
H. Ishihara;Y. Hirabayashi
以二酰基硒醚和氢氧化钾的甲醇溶液为原料，合成了硒代羧酸钾。它们在氮气下相当稳定，可用作制备硒代羧酸衍生物的起始原料：硒代苯甲酸甲酯、α-（硒代苯甲酰基）苯乙酮、苯基对氯苯甲酰基二硒醚、O-三甲基硅基硒代苯甲酸酯、双（硒代硬脂酰基）甲烷和二苯甲酰基二硒醚。
Potassium selenocarboxylates were prepared in good yields on the reaction of diacyl selenides with methanolic potassium hydroxide. They were fairly stable under nitrogen and useful as starting material for the preparation of selenocarboxylic acid derivatives; methyl selenobenzoate, α-(selenobenzoyl)acetophenone, phenyl p-chlorobenzoyl diselenide, O-trimethylsilyl selenobenzoate, bis(selenostearoyl)methane, and dibenzoyl diselenide.