Selective synthesis of Rh5 carbonyl clusters within a polyamine dendrimer for chemoselective reduction of nitro aromatics
Selective synthesis of Rh5 carbonyl clusters within a polyamine dendrimer for chemoselective reduction of nitro aromatics
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DOI：
10.1039/c4cc00976b
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Kaneda, Kiyotomi
中科院分区：
文献类型：
--
作者：
Maeno, Zen;Mitsudome, Takato;Kaneda, Kiyotomi
成功地证明了[Rh-5(CO)(15)]（-）簇在PPI树状聚合物中的选择性合成。树状分子包封的[Rh-5(CO)(15)]（-）在催化反应条件下不易分解，在CO/H2O作还原剂的情况下，对各种硝基芳烃的硝基与其他可还原基团的化学选择性还原表现出极高的选择性。
The selective synthesis of the [Rh-5(CO)(15)](-) cluster within the PPI dendrimer was successfully demonstrated. The dendrimer-encapsulated [Rh-5(CO)(15)](-) was resistant to decomposition under the catalytic reaction conditions and exhibited extremely high selectivity for the chemo-selective reduction of nitro groups of various nitro aromatics with other reducible groups using CO/H2O as a reductant.