Borrowing Hydrogen. C—N Bond Formation from Alcohols
Borrowing Hydrogen. C—N Bond Formation from Alcohols
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DOI：
10.1002/chin.200935228
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发表时间：
2009-09
期刊：
影响因子：
--
通讯作者：
Gareth W. Lamb;Jonathan M. J. Williams
中科院分区：
文献类型：
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作者：
Gareth W. Lamb;Jonathan M. J. Williams
综述了利用醇和借氢策略对胺进行烷基化反应。烷基化过程产生水作为唯一的副产物，并由过渡金属络合物催化，将醇暂时氧化成更具活性的醛。
The alkylation of amines using alcohols with the borrowing hydrogen strategy is reviewed. The alkylation process generates water as the only by-product and is catalysed by transition metal complexes which temporarily oxidise the alcohol to a more reactive aldehyde.