Functional porphyrinic metal-organic frameworks: crystal engineering and applications.
Functional porphyrinic metal-organic frameworks: crystal engineering and applications.
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DOI：
10.1039/c2dt11989g
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发表时间：
2012-03
影响因子：
4
通讯作者：
Chao Zou;Chuande Wu
中科院分区：
文献类型：
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作者：
Chao Zou;Chuande Wu
金属有机骨架材料是一类能够在骨架骨架上整合功能基团的材料。可调功能使MOFs在发光、气体存储、传感、磁性、催化和生物医学成像等领域得到了广泛的应用。由于卟啉和金属卟啉具有结构稳定性、催化、电荷和能量转换等特性，利用卟啉和金属卟啉作为配体制备功能性MOFs引起了人们的极大兴趣。人们已经建立了许多有效的策略来构建功能卟啉MOFs，其中一些具有潜在的应用价值。本文综述了卟啉类MOFs的最新研究进展，包括新的合成策略和应用。
Metal-organic frameworks (MOFs) are a kind of material which are able to integrate functional groups on their framework backbones. The tunable functionalities let MOFs be applied in various fields of luminescence, gas storage, sensing, magnetics, catalysis and biomedical imaging. Because of their interesting properties of structural robustness, catalysis, charge and energy transformations, using porphyrins and metalloporphyrins as synthons for the fabrication of functional MOFs has attracted considerable interest. Many efficient strategies have been established for the construction of functional porphyrinic MOFs, and some of them present interesting properties for potential applications. This perspective is aimed to summarize recent progress on porphyrinic MOFs, including new synthesis strategies and applications.