Development of Rare Metal‐Free Synthetic Method Using New Iodine Reagents
Development of Rare Metal‐Free Synthetic Method Using New Iodine Reagents
复制标题
使用新型碘试剂开发无稀有金属合成方法
DOI：
10.1002/chin.201013268
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
T. Dohi
中科院分区：
文献类型：
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作者：
T. Dohi
氧化是一种重要的官能团转化和成键方法，高价碘具有低毒、易操作等优点，是开发环境友好氧化反应的理想试剂之一。我们的研究目的是通过开拓它们的有效利用方法和独特的新反应活性，提高这些试剂作为剧毒重金属氧化剂甚至稀有过渡金属的有用替代品的合成价值。
Oxidation is synthetically important as functional group transformation and bond-forming method, and hypervalent iodines are one of the promising reagents for development of environmentally benign oxidations due to their low toxicities and easy handling. Our research purpose is to enhance the synthetic values of the reagents as useful alternatives to highly toxic heavy metal oxidants and even rare-transition metals, by pioneering their efficient utilization methods and unique new reactivities.