Temperature-controlled self-assembled synthesis of CuO,Cu2O and Cu nanoparticles through a single-precursor route
Temperature-controlled self-assembled synthesis of CuO,Cu2O and Cu nanoparticles through a single-precursor route
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通过单前体途径温控自组装合成 CuO、Cu2O 和 Cu 纳米颗粒
DOI:
10.1016/j.msea.2006.08.104
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发表时间:
2007-03-15
期刊:
影响因子:
6.4
通讯作者:
Liu, Xianming
中科院分区:
文献类型:
--
作者:
Liu, Xiaowang;Geng, Baoyou;Liu, Xianming
In this paper. we report on the synthesis of CuO, Cu2O and Cu nanoparticles through a single-precursor route by controlling the growth temperature. CuO and Cu2O nanoparticles have nanoporous structural configurations composed of a large number of primary particles. According to the difference between the crystal planes, we proposed the possible growth mechanisms of CuO, Cu2O and Cu nanoparticles. Selective adsorption of oleylamine on various crystal planes may play an important role in the growth process. The understanding of this self-assembling process will help us to develop reliable and reproducible methods to synthesis other three dimensional nanostructured architectures and increase the knowledge of self-assembly. (c) 2006 Elsevier B.V. All rights reserved.