Design of a combinational magnesium catalyst for the stereocontrolled cross reaction of enones.
Design of a combinational magnesium catalyst for the stereocontrolled cross reaction of enones.
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DOI：
10.1002/chem.201403183
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发表时间：
2014-07
期刊：
影响因子：
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通讯作者：
Dongxu Yang;Linqing Wang;F. Han;Depeng Zhao;Rui Wang
中科院分区：
文献类型：
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作者：
Dongxu Yang;Linqing Wang;F. Han;Depeng Zhao;Rui Wang
首次实现了烯酮的立体控制交叉反应。设计了一种新型的组合镁催化剂，以解决具有分子间对称结构和带有相同官能团的反应伙伴之间的对映选择性问题。这种新的催化策略被证明是有效的，在烯酮的交叉反应中引入高水平的对映选择性。
The first stereocontrolled cross reaction of enones has been realized. A novel combinational magnesium catalyst was designed to address the enantioselectivity problem between reaction partners with an intermolecular symmetric structure and bearing identical functional groups. This new catalytic strategy was proven to be effective to introduce high levels of enantioselectivity in the cross reaction of enones.