PERMEATION, DIFFUSION, AND SOLUBILITY OF DEUTERIUM IN PYREX GLASS.

PERMEATION, DIFFUSION, AND SOLUBILITY OF DEUTERIUM IN PYREX GLASS.
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氘在派热克斯玻璃中的渗透、扩散和溶解度。

DOI:
10.1063/1.1670770
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发表时间:
1969
影响因子:
4.4
通讯作者:
P. J. Jorgensen
P. J. Jorgensen
中科院分区:
化学2区
文献类型:
--
作者:
H. M. Laska;R. Doremus;P. J. Jorgensen

文献摘要

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The permeation of deuterium through thin Pyrex bulbs was measured with a mass spectrometer. The activation energies and absolute values at 200°C for permeation and diffusion were nearly the same as for deuterium in fused silica. The solubility of deuterium in Pyrex was independent of temperature, and about the same as the solubilities of several gases in fused silica. These results are consistent with a free‐volume theory of gas solubility in glass and the separation of Pyrex into silica and sodium borosilicate phases.