Ligand driven σ,π-η3 structural rearrangements of organopalladium complexes: their relevance to the CO/styrene copolymerisation reaction

Ligand driven σ,π-η3 structural rearrangements of organopalladium complexes: their relevance to the CO/styrene copolymerisation reaction
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配体驱动的有机钯配合物的 σ,π-η3 结构重排:它们与 CO/苯乙烯共聚反应的相关性

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发表时间:
2000
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影响因子:
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通讯作者:
E. Zangrando
E. Zangrando
中科院分区:
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文献类型:
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作者:
B. Milani;Federica Paronetto;E. Zangrando

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报道了一种钯(II) π-烯丙基化合物的晶体结构及其在溶液中的完整表征。其化学行为对Pd(II)配合物促进CO/苯乙烯共聚的机理有一定的启示。
The crystal structure and the full characterisation in solution of a palladium(II)–π-allylic compound is reported; its chemical behaviour may shed some light on the mechanism of the CO/styrene copolymerisation promoted by Pd(II) complexes.