Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde
Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde
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DOI：
10.1039/b717261c
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发表时间：
2008-03-21
影响因子：
4.9
通讯作者：
Kurosawa, Hideo
中科院分区：
文献类型：
--
作者：
Ogoshi, Sensuke;Arai, Tomoya;Kurosawa, Hideo
已证明，通过用镍（0）氧化环化炔和醛可以形成二氢呋喃镍;二氢呋喃镍通过分解转化为烯酮，通过羰基化转化为内酯，并通过用ZnMe（2）处理转化为烯丙型醇，表明二氢呋喃镍是多种催化反应中的重要关键中间体。
The formation of a nickeladihydrofuran by oxidative cyclization of an alkyne and an aldehyde with nickel(0) has been demonstrated; the transformation of the nickeladihydrofuran into an enone by decomposition, a lactone by carbonylation and an allylic alcohol by treatment with ZnMe(2) suggests that nickeladihydrofuran is an important key intermediate in a variety of catalytic reactions.