Silver assisted crack healing in SiC

Silver assisted crack healing in SiC
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DOI:
10.1016/j.actamat.2015.11.052
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发表时间:
2016-02
期刊:
影响因子:
9.4
通讯作者:
Xin Geng;Fan Yang;Yiqiang Chen;Xiaoxiao Lu;X. Zhong;P. Xiao
Xin Geng;Fan Yang;Yiqiang Chen;Xiaoxiao Lu;X. Zhong;P. Xiao
中科院分区:
材料科学1区
文献类型:
--
作者:
Xin Geng;Fan Yang;Yiqiang Chen;Xiaoxiao Lu;X. Zhong;P. Xiao

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本文提出了一种通过溶解-析出机制实现SiC在1450℃真空热处理中裂纹愈合的潜在方法。热力学计算和实验结果证实,Ag与SiC反应形成熔融的Ag - si合金和碳,加速了材料在SiC中的输运,然后Ag - si与碳反应形成新的SiC并填充在裂纹和维氏压痕内,实现了SiC裂纹的愈合。压痕的深度回收率为~ 60%。压痕下的裂纹断裂成一排孤立的结核,这是由于SiC与Ag-Si合金之间的界面能降低所致。
This paper provides a potential method through a dissolution-precipitation mechanism to achieve crack healing in SiC by a vacuum heat treatment with Ag at 1450 °C. The thermodynamic calculations and experimental results confirm that the Ag reacts with SiC to form a molten Ag–Si alloy and carbon, which accelerates material transport in SiC, and then by reaction between the Ag–Si and carbon, a new SiC is formed and fills inside the cracks and Vickers indentation impressions to achieve crack healing in SiC. The depth recovery ratio of the indentation is ∼60%. The cracks underneath the indentation break into a row of isolated nodules, which is driven by reducing the interfacial energy between SiC and the Ag–Si alloy.