Synthesis of a Dendrimer Reactor for Clusters with a Magic Number
Synthesis of a Dendrimer Reactor for Clusters with a Magic Number
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DOI：
10.1246/cl.2012.828
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发表时间：
2012-08-05
影响因子：
1.6
通讯作者：
Yamamoto, Kimihisa
中科院分区：
文献类型：
--
作者：
Kitazawa, Hirokazu;Albrecht, Ken;Yamamoto, Kimihisa
以“幻数13”金属簇为模板，合成了一种新型的苯基甲亚胺树状大分子（DPA），该大分子比四苯基甲烷多一个配位点，具有立方或六方密排结构.研究表明，该配合物具有逐级络合的性质，有望成为“幻数13”金属簇合物的模板。
A new type of phenylazomethine dendrimer (DPA) that has one more coordination site compared to the tetraphenylmethane core DPA was synthesized for the "magic number 13" metal cluster template that has cubic or hexagonal densely packed structures. The stepwise complexation property was revealed, and this property is expected to be the "magic number 13" metal cluster template.