Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
复制标题
钯催化缺电子多氟芳烃与芳基硼酸的直接芳基化
DOI：
10.1021/ol901200g
复制
发表时间：
2009-08-06
期刊：
影响因子：
5.2
通讯作者：
Hong, Maochun
中科院分区：
文献类型：
--
作者：
Wei, Ye;Kan, Jian;Hong, Maochun
实现了钯催化的含两个或多个氟基团的缺电子芳烃与芳基硼酸的直接芳基化反应。实现多氟苯和芳基硼酸的广泛底物范围的关键是根据多氟苯的酸度选择碱。
The palladium-catalyzed direct arylation of electron-deficient arenes that contain two or more fluorine groups with arylboronic acids was realized. The key to achieving a broad substrate scope with respect to both polyfluorobenzenes and arylboronic acids is the choice of bases depending on acidities of polyfluorobenzenes.