Effect of Ferrite on the Precipitation of σ Phase in Cast Austenitic Stainless Steel Used for Primary Coolant Pipes of Nuclear Power Plants

Effect of Ferrite on the Precipitation of σ Phase in Cast Austenitic Stainless Steel Used for Primary Coolant Pipes of Nuclear Power Plants
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铁素体对核电站一次冷却剂管道用铸造奥氏体不锈钢α相析出的影响

DOI:
10.1590/1980-5373-mr-2017-0209
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发表时间:
2017-09
期刊:
Materials Research
影响因子:
--
通讯作者:
Na Li
Na Li
中科院分区:
其他
文献类型:
--
作者:
Yongqiang Wang;Na Li

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采用等温热处理、光学显微镜(OM)、透射电镜(TEM)和电子探针显微分析(EPMA)等方法研究了Z3 CN 20. 09 M铸造奥氏体不锈钢(卡斯)中铁素体相对σ相析出的影响。讨论了铁素体的不同形态和体积分数对σ相形成机制的影响。随着时效时间的延长,不同组织试样中σ相的析出量均增加,但析出速率有显著差异。粗大铁素体和弥散细小铁素体的试样中σ相的形成最慢。铁素体中Cr含量最低和试样中α/γ界面最少是σ析出最慢的主要原因,它们分别不利于相变动力学和热力学。而窄长铁素体组织中σ相的形成速度最快,这是由于铁素体中存在较多的α/γ界面和较高的Cr含量,有利于σ相的优先形核和形成热力学。
The effect of ferrite phase on the precipitation of σ phase in a Z3CN20.09M cast austenitic stainless steel (CASS) used for primary coolant pipes of pressurized water reactor (PWR) nuclear power plants was investigated by using isothermal heat-treatment, optical microscopy (OM), transmission electron microscopy (TEM) and electron probe microanalysis (EPMA) techniques. The influence of different morphologies and volume fractions of ferrite in the σ phase formation mechanism was discussed. The amount of σ phase precipitated in all specimens with different microstructures increased with increasing of aging time, however, the precipitation rate is significant different. The formation of σ phase in specimens with the coarsest ferrite and the dispersively smallest ferrite is slowest. The lowest level Cr content in ferrite and fewest α/γ interfaces in specimen are the main reasons for the slowest σ precipitation due to they are unfavorable for the kinetics and thermodynamics of phase transformation respectively. By contraries, the fastest formation of σ phase takes place in specimens with narrow and long ferrite due to the most α/γ interfaces and higher Cr content in ferrite which are beneficial for preferential nucleation and formation thermodynamics of σ phase.
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