Synthesis, Photophysics, Electrochemistry, and Reactivity of Ruthenium(II) Polypyridine Complexes with Organoplatinum(II) Moieties. Crystal Structure of [Ru(bpy)2(μ-2,3-dpp)PdCl2]2+
Synthesis, Photophysics, Electrochemistry, and Reactivity of Ruthenium(II) Polypyridine Complexes with Organoplatinum(II) Moieties. Crystal Structure of [Ru(bpy)2(μ-2,3-dpp)PdCl2]2+
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[Ru(bpy)2(μ-2,3-dpp)PdCl2]2+ 与有机铂 (II) 部分的钌 (II) 聚吡啶配合物的合成、光物理、电化学和反应性。
DOI：
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发表时间：
1997
期刊：
影响因子：
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通讯作者：
K. Cheung
中科院分区：
文献类型：
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作者：
V. Yam;V. Lee;K. Cheung
一系列含有机铂(II)的Ru(II)多吡啶发光配合物及其氯前体和钯(II)二氯类似物，[Ru(Bpy)2(BL)MX2]2+(BL=2，3-DPP，M=Pd，X=Cl(1)；M=Pt，X=Cl(2)，Cl和CH3(3)，CH3(4)，C6H5(5)，C6H4-OCH3-p(6)，C6H4-F-p(7)；bpm，M=Pd，X=Cl(8)；合成了M=铂，X=氯(9)，氯和CH3(10)，C6H5(11)，C6H4-CH3-o(12)，C6H4-OCH3-p(13)，C6H4-F-p(14)；BL=2，3-DPQ，M=PT，R=C6H4-OCH3-p(15)，并研究了它们的电化学和光物理性质，考察了它们对甲基碘氧化加成反应的活性。测定了1的X-射线晶体结构。
A series of luminescent ruthenium(II) polypyridine complexes with organoplatinum(II) moieties, together with their chloro precursors and palladium(II) dichloro analogues, [Ru(bpy)2(BL)MX2]2+ (BL = 2,3-dpp, M = Pd, X = Cl (1); M = Pt, X = Cl (2), Cl and CH3 (3), CH3 (4), C6H5 (5), C6H4-OCH3-p (6), C6H4-F-p (7); BL = bpm, M = Pd, X = Cl (8); M = Pt, X = Cl (9), Cl and CH3 (10), C6H5 (11), C6H4-CH3-o (12), C6H4-OCH3-p (13), C6H4-F-p (14); BL = 2,3-dpq, M = Pt, R = C6H4-OCH3-p (15)) have been synthesized and their electrochemical and photophysical properties studied; their reactivities toward the oxidative addition of methyl iodide have been investigated. The X-ray crystal structure of 1 has been determined.