Boron Nitride Mesoporous Nanowires with Doped Oxygen Atoms for the Remarkable Adsorption Desulfurization Performance from Fuels
Boron Nitride Mesoporous Nanowires with Doped Oxygen Atoms for the Remarkable Adsorption Desulfurization Performance from Fuels
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掺杂氧原子的氮化硼介孔纳米线具有显着的燃料吸附脱硫性能
DOI：
10.1021/acssuschemeng.6b01156
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发表时间：
2016-06
影响因子：
8.4
通讯作者：
Li Huaming
中科院分区：
文献类型：
--
作者：
Xiong Jun;Yang Lei;Chao Yanhong;Pang Jingyu;Zhang Ming;Zhu Wenshuai;Li Huaming
成功控制并制备了掺杂氧原子的新型BN介孔纳米线材料。已采用多种技术来确定结构、形态、表面特征、缺陷和电子结构。这是首次将这种独特结构的受控制备应用于吸附脱硫。所得BN介孔纳米线对DBT（根据Langmuir等温线模型为65.4 mg S g-1吸附剂）表现出出色的吸附脱硫活性，远高于商业BN和类石墨烯BN。同时，BN介孔纳米线对4,6-DMDBT（33.2 mg S g-1吸附剂）表现出良好的稳定性和优异的吸附性能。 BN介孔纳米线吸附脱硫性能的显着增强归因于纳米线表面和介孔上存在大量低配位原子，这些原子可以与DBT以及掺杂氧发生相互作用。
Novel BN mesoporous nanowire materials with doped oxygen atoms have been controlled and prepared successfully. Multiple techniques have been employed to determine the structure, morphology, surface feature, defects, and electronic structure. It was the first time that a controlled preparation of this unique structure was applied to adsorptive desulfurization. The obtained BN mesoporous nanowires displayed outstanding adsorptive desulfurization activity for DBT (65.4 mg S g–1 adsorbent according to the Langmuir isotherm model), which was much higher than that of commercial BN and graphene-like BN. At the same time, the BN mesoporous nanowires displayed good stability and excellent adsorption performance for the 4,6-DMDBT (33.2 mg S g–1 adsorbent). The significant enhancement of adsorption desulfurization performance of BN mesoporous nanowires was ascribed to the large number of low coordinated atoms along the nanowire surface and mesopores, which could cause an interaction with DBT, and the doped oxygen at...
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影响因子：
22.1
作者：
Song, C;Ma, XL
通讯作者：
Ma, XL
影响因子：
4.2
作者：
Jing Xiao;C. Song;Xiaoliang Ma;Zhong Li
通讯作者：
Jing Xiao;C. Song;Xiaoliang Ma;Zhong Li
具有碳空位的多孔石墨氮化碳纳米片可显着提高光催化产氢能力
影响因子：
19
作者：
Liang, Qinghua;Li, Zhi;Yang, Quan-Hong
通讯作者：
Yang, Quan-Hong
影响因子：
10.9
作者：
M. Seredych;T. Bandosz
通讯作者：
M. Seredych;T. Bandosz
影响因子：
3.7
作者：
Yawei Shi;Xiangwen Zhang;Li Wang;Guozhu Liu
通讯作者：
Yawei Shi;Xiangwen Zhang;Li Wang;Guozhu Liu