New framework connectivity patterns in templated networks:: The creatinine zinc phosphites C4N3OH7•ZnHPO3, C4N3OH7•Zn(H2O)HPO3, and (C4N3OH7)2•ZnHPO3-H2O
New framework connectivity patterns in templated networks:: The creatinine zinc phosphites C4N3OH7•ZnHPO3, C4N3OH7•Zn(H2O)HPO3, and (C4N3OH7)2•ZnHPO3-H2O
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DOI：
10.1021/ic020593
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发表时间：
2003-03-10
影响因子：
4.6
通讯作者：
Nenoff, TM
中科院分区：
文献类型：
--
作者：
Harrison, WTA;Yeates, RM;Nenoff, TM
C4N3OH7的合成、晶体结构和性质。ZnHPO3 C4N3OH7。Zn(H2O)HPO3和（C4N3OH7）(2)。ZnHPO3。H2O被报道。这些新的肌酸酐亚磷酸锌由顶点共享的HPO3假金字塔和各种类型的ZnO2N2、ZnO3N和ZnO2N（H2O）四面体网络构建而成，从而形成不同维度的扩展结构（分别为片状、簇状和链状）。他们证明了将“末端”（非网络）Zn-N和Zn-OH2基团纳入锌中心的结构效应。晶体数据：C4N3OH7。ZnHPO3，三斜，P1 (No. 2), a = 8.9351(4)埃，b = 9.5011(4)埃，c = 9.9806(4)埃，alpha = 87.451(1)度，beta = 85.686(1)度，gamma = 89.551(1)度，Z = 4；C4N3OH7。Zn(H2O)HPO3，单斜，P2(1)/c (No. 14), a = 10.1198(7)埃，b = 7.2996(5)埃，c = 13.7421(9)埃，β = 107.522(1)度，Z = 4；(2) .ZnHPO3 (C4N3OH7)。H2O，三斜，P1 (No. 2), a = 10.7289(6)埃，b = 10.9051(6)埃，c = 13.9881(8)埃，alpha = 89.508(1)度，beta = 74.995(1)度，gamma = 74.932(1)度，Z = 4。
The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.