Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers.
Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers.
复制标题
DOI：
10.1039/c3cc39066g
复制
发表时间：
2013-02
影响因子：
4.9
通讯作者：
P. W. Chia;D. Bello;A. Slawin;D. O'Hagan
中科院分区：
文献类型：
--
作者：
P. W. Chia;D. Bello;A. Slawin;D. O'Hagan
由Ruppert-Prakash试剂生成的二氟卡宾(CF(2))与乙炔醚反应，意外地产生了共同生成的含氟双环[2.1.1]-六-2-烯和环庚烷-1，4-二烯。
The reaction of acetylene ethers with difluorocarbene (CF(2)), generated from the Ruppert-Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.