Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3
Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3
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DOI：
10.1016/0021-9517(65)90163-6
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发表时间：
1965-10
影响因子：
7.3
通讯作者：
A. Bleijenberg;B. C. Lippens;G. Schuit
中科院分区：
文献类型：
--
作者：
A. Bleijenberg;B. C. Lippens;G. Schuit
在Bi2O_3-MoO_3体系中，确定了如下化合物：(1)Bi2O_3·3MoO_3=Bi2(MoO_4)_3MP_(676)C_2。(2)Bi2O_3·MoO_3=Bi2MoO_6=(BiO)_2MoO_4 MP_938 C。(3)3Bi2O_3·MoO_3=Bi6MoO_12 MP 995 C。对该体系中烧结混合物的X射线研究证实了这三种化合物的存在。未检测到化合物Bi2O32MoO3。
In the system Bi2O3---MoO3 the following compounds were identified: 1.(1) Bi2O3· 3MoO3= Bi2 (MoO4) 3 mp 676 C 2.(2) Bi2O3· MoO3= Bi2MoO6=(BiO) 2MoO4 mp 938 C 3.(3) 3Bi2O3· MoO3= Bi6MoO12 mp 995 C These compounds were found by investigation of the phase diagram of the Bi2O3---MoO3 binary system by means of thermal analysis. X-ray studies of sintered mixtures in this system confirmed the existence of the three compounds. A compound Bi2O3· 2MoO3 could not be detected.