Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution.
Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution.
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DOI：
10.1039/c0cc03111a
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发表时间：
2010-11
影响因子：
4.9
通讯作者：
Xiao‐lan Tong;Tong‐Liang Hu;Jiongpeng Zhao;Yuekui Wang;Hui Zhang;X. Bu
中科院分区：
文献类型：
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作者：
Xiao‐lan Tong;Tong‐Liang Hu;Jiongpeng Zhao;Yuekui Wang;Hui Zhang;X. Bu
配合物1(1a和1b)的对映体是在没有手性源的情况下通过晶化自发拆分得到的。通过圆二色谱(CD)和理论研究证实了1a和1b的对映体性质。
The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.