Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation
Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation
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DOI：
10.1016/j.apcata.2016.03.010
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发表时间：
2016-05-05
影响因子：
5.5
通讯作者：
Gavgani, Jaber Nasrollah
中科院分区：
文献类型：
--
作者：
Mahyari, Mojtaba;Bide, Yasamin;Gavgani, Jaber Nasrollah
在这项研究中，我们报道了负载在S和N共掺杂石墨烯量子点（S，N：GQD）上的Fe（III）四（4-磺基苯基）卟啉（FeTSPP）的合成和令人印象深刻的性能，作为高效、可回收且不含贵金属的非均相光催化剂，用于将醇选择性有氧氧化成相应的羰基化合物。研究发现，FeTSPP@S,N:GQDs 光催化剂具有一种新颖的化学功能，可用于有效的可见光催化有氧醇氧化，在室温下作为绿色溶剂在水中具有良好的转化率和选择性。我们预计 FeTSPP@S, N: GQD 为开发高活性精细化工生产中的高效、可回收和工业适用的光催化剂提供了一个有前途的候选者。 (C) 2016 Elsevier B.V. 保留所有权利。
In this study, we report the synthesis and impressive performance of Fe(III)tetra(4-sulfonatophenyl)porphyrins (FeTSPP) supported on S and N co-doped graphene quantum dots (S, N: GQDs) as efficient, recyclable, and noble metal free heterogeneous photocatalyst for the selective aerobic oxidation of alcohols to the corresponding carbonyl compounds. It was found that FeTSPP@S, N: GQDs photocatalyst represents a novel chemical function for efficient visible light catalyzed aerobic alcohol oxidation with good conversions and selectivity in water as a green solvent at room temperature. We envision that FeTSPP@S, N: GQDs provide a promising candidate for the development of highly efficient, recyclable, and industrially applicable photocatalyst in fine chemical production with high activity. (C) 2016 Elsevier B.V. All rights reserved.