Novel synthetic approach to creating PtCo alloy nanoparticles by reduction of metal coordination nano-polymers.
Novel synthetic approach to creating PtCo alloy nanoparticles by reduction of metal coordination nano-polymers.
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DOI：
10.1039/b508182c
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发表时间：
2005-09
影响因子：
4.9
通讯作者：
M. Yamada;M. Maesaka;M. Kurihara;M. Sakamoto;M. Miyake
中科院分区：
文献类型：
--
作者：
M. Yamada;M. Maesaka;M. Kurihara;M. Sakamoto;M. Miyake
采用铂(IV)/四氰基铂酸钴金属配位纳米聚合物(Pt(II)-CN-Pt(IV)/Co)的转化反应通过氢气气相还原，通过一种新颖的合成方法制备了具有不同金属元素比例(Pt/Co = 0.9、1.6、2.9和3.6)的PtCo合金纳米粒子。
PtCo alloy nanoparticles with different metal elemental ratios (Pt/Co = 0.9, 1.6, 2.9, and 3.6) were prepared by a novel synthetic approach, using the transformation reaction of platinum(IV)/cobalt tetracyanoplatinate metal coordination nano-polymers (Pt(II)-CN-Pt(IV)/Co)via a H2 gas-phase reduction.