Kinetic Stabilization of a Ni(II) Bis(dithiobenzoate)-type Complex Achieved Using Three-dimensional Insulation by a [1]Rotaxane Structure
Kinetic Stabilization of a Ni(II) Bis(dithiobenzoate)-type Complex Achieved Using Three-dimensional Insulation by a [1]Rotaxane Structure
复制标题
[1]Rotaxane 结构利用三维绝缘实现 Ni(II) 双（二硫代苯甲酸酯）型配合物的动力学稳定性
DOI：
10.1039/c8cc00351c
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发表时间：
2018
期刊：
影响因子：
--
通讯作者：
Jun Terao
中科院分区：
文献类型：
--
作者：
Takuro Hosomi;Ryosuke Harada;Hiroshi Masai;Tetsuaki Fujihara;Yasushi Tsuji;Jun Terao
我们在此描述的合成的Ni（II）双（二硫代苯甲酸酯）型配合物三维绝缘的[1]轮烷结构，以揭示绝缘的重要性。在循环伏安法条件下，该配合物显示出稳定和可逆的氧化还原行为，与非绝缘的参比配合物相反，清楚地证明了轮烷型绝缘作为动力学金属配合物稳定化的新方法的有效性。
We describe herein the synthesis of a Ni(II) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Under cyclic voltammetry conditions, the complex showed a stable and reversible redox behavior in contrast to a non-insulated reference complex, clearly demonstrating the effectiveness of the rotaxane-type insulation as a new method of kinetic metal complex stabilization.