Porphyrins Sheathed in Quadrupolar Solvation Spheres of Hexafluorobenzene: Solvation-Induced Fluorescence Enhancement and Conformational Confinement
Porphyrins Sheathed in Quadrupolar Solvation Spheres of Hexafluorobenzene: Solvation-Induced Fluorescence Enhancement and Conformational Confinement
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六氟苯四极溶剂化球包裹的卟啉：溶剂化诱导的荧光增强和构象限制
DOI：
10.1021/acs.jpcc.7b04083
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
Ikeda Noriaki
中科院分区：
文献类型：
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作者：
Morisue Mitsuhiko;Ueno Ikuya;Shimizu Masaki;Yumura Takashi;Ikeda Noriaki
六氯苯（C6F6）通过四极相互作用强溶剂化卟啉环。C6F6的溶剂化球阻碍了卟啉环附近的热涨落，激发了卟啉显着的光电性质，如荧光增强和光谱锐化。
Hexafluorobenzene (C6F6) strongly solvated the porphyrin ring via a quadrupolar interaction. The solvation sphere of C6F6hindered the thermal fluctuations near the porphyrin ring and evoked remarkable photoelectronic properties of the porphyrins such as fluorescence enhancement and spectral sharpening due to confined torsional planarity.