Electrochemically Supported Deoxygenation of Epoxides into Alkenes in Aqueous Solution

Electrochemically Supported Deoxygenation of Epoxides into Alkenes in Aqueous Solution
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水溶液中电化学支持环氧化物脱氧成烯烃

DOI:
10.1021/ol2026944
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发表时间:
2012-01-06
期刊:
影响因子:
5.2
通讯作者:
Chen, Dong-Song
Chen, Dong-Song
中科院分区:
化学1区
文献类型:
--
作者:
Huang, Jing-Mei;Lin, Zhi-Quan;Chen, Dong-Song

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研究了在饱和NH4Br和四氢呋喃(8:1)的混合物中,在配有一对锌电极的未分裂电池中,由环氧化物高效合成烯烃的方法,并提出了该反应是由具有层次组织的纳米结构的Zn(0)介导的。
An efficient synthesis of alkenes from epoxides in a mixture of saturated aqueous NH4Br and tetrahydrofuran (8:1) has been developed in an undivided cell fitted with a pair of zinc electrodes, and it is proposed that the reaction Is mediated by Zn(0) with a hierarchically organized nanostructu re.