Fluctuation theorem for nonequilibrium reactions
Fluctuation theorem for nonequilibrium reactions
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DOI：
10.1063/1.1688758
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发表时间：
2004-05-15
影响因子：
4.4
通讯作者：
Gaspard, P
中科院分区：
文献类型：
--
作者：
Gaspard, P
本文导出了由化学主方程控制的随机非平衡反应的涨落定理。该定理表示的生成函数和大偏差函数的波动量，衡量损失的详细平衡的热力学平衡。与熵产生的关系建立和讨论。涨落定理在Schlogl远离平衡双稳模型中得到了验证。(C)2004年，美国物理学会。
A fluctuation theorem is derived for stochastic nonequilibrium reactions ruled by the chemical master equation. The theorem is expressed in terms of the generating and large-deviation functions characterizing the fluctuations of a quantity which measures the loss of detailed balance out of thermodynamic equilibrium. The relationship to entropy production is established and discussed. The fluctuation theorem is verified in the Schlogl model of far-from-equilibrium bistability. (C) 2004 American Institute of Physics.