The Kumada-Tamao-Corriu Coupling Reaction Catalyzed by Rhodium-Aluminum Bimetallic Complexes
The Kumada-Tamao-Corriu Coupling Reaction Catalyzed by Rhodium-Aluminum Bimetallic Complexes
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DOI：
10.1021/acs.orglett.2c01060
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发表时间：
2022-04-19
期刊：
影响因子：
5.2
通讯作者：
Nakao, Yoshiaki
中科院分区：
文献类型：
--
作者：
Fujii, Ikuya;Semba, Kazuhiko;Nakao, Yoshiaki
铑 - 铝双金属配合物催化熊田 - 玉尾 - 科里（KTC）交叉偶联反应，该反应使用由这些催化剂原位从相应的芳基氟化物或氯化物生成的芳基镁化合物。这种方法使得具有挑战性的KTC偶联反应能够使用芳基氟化物作为亲核试剂进行，从而得到各种联芳基化合物。
Rhodium-aluminum bimetallic complexes catalyze the Kumada-Tamao-Corriu (KTC) cross-coupling reaction using arylmagnesium compounds that are generated from the corre-sponding aryl fluorides or chlorides in situ by these catalysts. This method allows the challenging KTC coupling reaction to be carried out using aryl fluorides as nucleophiles, which affords various biaryls.