Formation of Copper Phthalocyanine Thin Films by Electrolysis of Surfactants with Ferrocenyl Moiety
Formation of Copper Phthalocyanine Thin Films by Electrolysis of Surfactants with Ferrocenyl Moiety
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电解二茂铁基表面活性剂形成铜酞菁薄膜
DOI：
10.1149/1.2096381
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发表时间：
1989
影响因子：
3.9
通讯作者：
Y. Ishii
中科院分区：
文献类型：
--
作者：
T. Saji;Y. Ishii
最近，作者提出了一种通过破坏具有二茂铁基部分的阳离子表面活性剂形成的胶束聚集体的电化学形成有机薄膜的新技术（MD法）。他们报道了制备不含金属的高浓度自由FPEG，而不吸附在CuPc颗粒上。CuPc粉末及其胶束溶液和薄膜之间的吸收光谱和x射线衍射图的一致性表明，在整个薄膜制备过程中，CuPc的晶体形态保持不变。本文的研究结果表明，MD法是制备具有理想晶型的CuPc薄膜的一种方便的方法。
Recently, the authors presented a novel technique for electrochemical formation of an organic thin film by disruption of micellar aggregates formed by cationic surfactants having a ferrocenyl moiety (MD method). They reported the preparation of metal-free high concentration of free FPEG not adsorbed on the CuPc particles. The agreements of absorption spectra and x-ray diffraction patterns among CuPc powders, their micellar solutions, and their films indicate that the crystalline form of CuPc is maintained throughout the film preparation processes. The results of the study presented in this paper demonstrate that the MD method is a convenient method to prepare a thin film of CuPc which has a desired crystalline form.