AUTOMATIC SENSITIVITY ANALYSIS OF KINETIC MECHANISMS
AUTOMATIC SENSITIVITY ANALYSIS OF KINETIC MECHANISMS
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DOI：
10.1002/kin.550110408
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发表时间：
1979-01-01
影响因子：
1.5
通讯作者：
SEINFELD, JH
中科院分区：
文献类型：
--
作者：
KODA, M;MCRAE, GJ;SEINFELD, JH
报道了一种基于Shuler及其同事的傅里叶幅度灵敏度检验(FAST)方法的运动机构灵敏度自动分析算法。该算法计算每个浓度对每个感兴趣的参数的相对敏感度，例如速率常数、阿累尼乌斯参数、化学计量系数和初始浓度。允许参数大小的任意变化。给出了计算A+A→两个阿累尼乌斯参数变化对物种A浓度敏感性的简单算例。
An algorithm for the automatic sensitivity analysis of kinetic mechanisms based on the Fourier amplitude sensitivity test (FAST) method of Shuler and co‐workers is reported. The algorithm computes a measure of the relative sensitivity of each concentration to each parameter of interest, such as rate constants, Arrhenius parameters, stoichiometric coefficients, and initial concentrations. Arbitrary variations in the magnitude of the parameters are allowable. The algorithm is illustrated for the simple example of computing the sensitivity of the concentration of species A to variation of the two Arrhenius parameters for the hypothetical reactionA+A→.